Method for manufacturing back surface incident type semiconductor photo detection element

ABSTRACT

A semiconductor substrate including a first main surface and a second main surface opposing each other is provided. The semiconductor substrate includes a first semiconductor region of a first conductivity type. The semiconductor substrate includes a plurality of planned regions where a plurality of second semiconductor regions of a second conductivity type forming pn junctions with the first semiconductor region are going to be formed, in a side of the second main surface. A textured region is formed on surfaces included in the plurality of planned regions, in the second main surface. The plurality of second semiconductor regions are formed in the plurality of planned regions after forming the textured region. The first main surface is a light incident surface of the semiconductor substrate.

TECHNICAL FIELD

The present invention relates to a method for manufacturing aback-illuminated semiconductor photodetector.

BACKGROUND ART

Known back-illuminated semiconductor photodetectors that include asemiconductor substrate including a first main surface and a second mainsurface opposing each other (see Patent Literatures 1 and 2, forexample). In a back-illuminated semiconductor photodetector described inPatent Literature 2, a semiconductor substrate includes a firstsemiconductor region of a first conductivity type and a plurality ofsecond semiconductor regions of a second conductivity type. Thesemiconductor substrate includes the plurality of second semiconductorregions in a side of the second main surface. Each of the secondsemiconductor regions constitutes a pn junction with the firstsemiconductor region. The first main surface is a light incident surfaceof the semiconductor substrate. The plurality of second semiconductorregions include a textured surface. The textured surface is formed afterforming the second semiconductor region.

CITATION LIST Patent Literature

-   Patent Literature 1: US Patent Application Publication No.    2012/0313204-   Patent Literature 2: Japanese Unexamined Patent Publication No.    2011-023417

SUMMARY OF INVENTION Technical Problem

An object of one aspect of the present invention is to provide a methodfor manufacturing a back-illuminated semiconductor photodetector capableof further improving spectral sensitivity characteristics in a longwavelength range. An object of another aspect of the present inventionis to provide a back-illuminated semiconductor photodetector capable offurther improving spectral sensitivity characteristics in a longwavelength range with reliability. For example, the long wavelengthrange includes a near infrared wavelength range.

Solution to Problem

A method for manufacturing a back-illuminated semiconductorphotodetector according to one aspect of the present invention includesa process of providing a semiconductor substrate, a process of forming atextured region, and a process of forming a plurality of secondsemiconductor regions. The semiconductor substrate includes a first mainsurface and a second main surface opposing each other, and includes afirst semiconductor region of a first conductivity type. Thesemiconductor substrate includes a plurality of planned regions where aplurality of second semiconductor regions of a second conductivity typeforming pn junctions with the first semiconductor region are going to beformed, in a side of the second main surface. The first main surface isa light incident surface of the semiconductor substrate. In the processof forming the textured region, the textured region is formed onsurfaces included in the plurality of planned regions, in the secondmain surface. In the process of forming the plurality of secondsemiconductor regions, the plurality of second semiconductor regions areformed in the plurality of planned regions after forming the texturedregion.

In the manufacturing method according to the one aspect, theback-illuminated semiconductor photodetector is obtained in which thefirst regions of the second semiconductor regions include texturedsurfaces. Light in a long wavelength range has a small absorptioncoefficient as compared with light in a short wavelength range.Therefore, light in the long wavelength range that is incident on thesemiconductor substrate from the first main surface travels in thesemiconductor substrate, and reaches a surface of the textured region.The light having reached the surface of the texture region is reflectedor diffused at the surface of the textured region, and further travelsin the semiconductor substrate. The light in the long wavelength rangetravels a long distance within the semiconductor substrate, and thus isabsorbed by the semiconductor substrate. Consequently, theback-illuminated semiconductor photodetector obtained with the oneaspect improves spectral sensitivity characteristics in the longwavelength range.

Carriers generated due to absorption of light by the semiconductorsubstrate may be recombined in the second semiconductor region. Carriersrecombined in the second semiconductor region do not contribute todetection sensitivity. Therefore, the spectral sensitivitycharacteristics may deteriorate.

Recombination of carriers in the second semiconductor region tends tooccur in a configuration where a thickness of the second semiconductorregion is large as compared with in a configuration where the thicknessof the second semiconductor region is small.

In the manufacturing method according to the one aspect, the pluralityof second semiconductor regions are formed in the plurality of plannedregions after the textured region is formed on the second main surface.In a process where the textured regions are formed after forming theplurality of second semiconductor regions, the thickness of each of thesecond semiconductor regions inevitably increases to reliably preventthe texture region from reaching the pn junction. Therefore, in theprocess where the plurality of second semiconductor regions are formedafter forming the texture regions, the thickness of each of the secondsemiconductor regions can be reduced as compared with in the processwhere the textured regions are formed after forming the plurality ofsecond semiconductor regions. Consequently, the back-illuminatedsemiconductor photodetector obtained with the one aspect can furtherimprove the spectral sensitivity characteristics in the long wavelengthrange.

In the one aspect, the second semiconductor regions may be formed alongsurface shapes of the textured regions. In this case, the thickness ofeach of the second semiconductor regions can be further reduced.Therefore, the back-illuminated semiconductor photodetector obtainedwith this process can further improve the spectral sensitivitycharacteristics in the long wavelength range with reliability.

In the one aspect, the second semiconductor regions may be formed due toadding impurities of the second conductivity type into the plannedregions. In this case, the second semiconductor regions are easilyformed due to using an existing method.

In the one aspect, the second semiconductor regions may be formed due toforming a layer containing impurities of the second conductivity type onthe surfaces of the planned regions. In this case, the secondsemiconductor regions having small thicknesses are formed reliably andeasily.

In the one aspect, the impurities of the second conductivity type may beboron.

In the one aspect, the textured region may be formed on each of thesurfaces included in the plurality of planned regions.

Light having reached the surface of the textured area is reflected orscattered at the surface of the textured region as described above. Thelight reflected or scattered at the textured region travels in variousdirections crossing a thickness direction of the semiconductor substrateas compared with light reflected at a flat surface. Therefore, lightreflected or diffused at the surface of the textured region may traveltoward adjacent pixels, and cause crosstalk between the pixels.Crosstalk generates noise.

In a case where the textured region is formed on each of the surfacesincluded in the plurality of planned regions, the textured region tendsnot to be formed in a region other than the surfaces included in theplurality of planned regions. For example, the configuration where thetextured region is formed on each of the surfaces included in theplurality of planned regions reduces occurrence of crosstalk as comparedwith a configuration where the textured region is formed in the entiresecond main surface. Therefore, the back-illuminated semiconductorphotodetector obtained due to this process reduces occurrence ofcrosstalk.

A back-illuminated semiconductor photodetector according to anotheraspect of the present invention includes a semiconductor substrateincluding a first main surface and a second main surface opposing eachother. The first main surface is a light incident surface of thesemiconductor substrate. The semiconductor substrate includes a firstsemiconductor region of a first conductivity type, and a plurality ofsecond semiconductor regions. The plurality of second semiconductorregions are provided in a side of the second main surface, and form pnjunctions with the first semiconductor region. The plurality of secondsemiconductor region include a region including a textured surface. Thesecond semiconductor region is provided along the textured surface, inthe region including the textured surface.

As described above, the back-illuminated semiconductor photodetectoraccording to the other aspect can further improve the spectralsensitivity characteristics in the long wavelength range withreliability.

Advantageous Effects of Invention

One aspect of the present invention provides a method for manufacturinga back-illuminated semiconductor photodetector capable of furtherimproving spectral sensitivity characteristics in a long wavelengthrange. Another aspect of the present invention provides aback-illuminated semiconductor photodetector capable of furtherimproving spectral sensitivity characteristics in a long wavelengthrange with reliability.

BRIEF DESCRIPTION OF DRAWINGS

FIG. 1 is a plan view of a back-illuminated semiconductor photodetectoraccording to an embodiment.

FIG. 2 is a view illustrating a cross-sectional configuration of theback-illuminated semiconductor photodetector according to the presentembodiment.

FIG. 3 is a plan view illustrating a configuration of theback-illuminated semiconductor photodetector according to the presentembodiment.

FIG. 4 is an SEM image of a textured surface observed.

FIG. 5 is an SEM image of a textured surface observed.

FIG. 6 is a view illustrating a cross-sectional configuration of onepixel.

FIG. 7A, 7B and 7C are schematic diagrams illustrating an example of amanufacturing process of the back-illuminated semiconductorphotodetector according to the present embodiment.

FIG. 8A, 8B and 8C are schematic diagrams illustrating an example of themanufacturing process of the back-illuminated semiconductorphotodetector according to the present embodiment.

FIG. 9A, 9B and 9C are schematic diagrams illustrating an example of themanufacturing process of the back-illuminated semiconductorphotodetector according to the present embodiment.

FIG. 10 is a chart illustrating a distribution of impurityconcentration.

FIG. 11 is a view illustrating a cross-sectional configuration of anelectronic component device that includes the back-illuminatedsemiconductor photodetector according to the present embodiment.

FIG. 12 is a view illustrating a cross-sectional configuration of aback-illuminated semiconductor photodetector according to a firstmodification of the present embodiment.

FIG. 13 is a plan view illustrating a configuration of theback-illuminated semiconductor photodetector according to the firstmodification.

FIG. 14 is a view illustrating a cross-sectional configuration of anelectronic component device that includes the back-illuminatedsemiconductor photodetector according to the first modification.

FIG. 15 is a view illustrating a cross-sectional configuration of aback-illuminated semiconductor photodetector according to a secondmodification of the present embodiment.

FIG. 16 is a plan view illustrating a configuration of theback-illuminated semiconductor photodetector according to the secondmodification.

FIG. 17 is a view illustrating a cross-sectional configuration of aback-illuminated semiconductor photodetector according to a thirdmodification of the present embodiment.

FIG. 18 is a plan view illustrating a configuration of theback-illuminated semiconductor photodetector according to the thirdmodification.

FIG. 19 is a plan view illustrating a configuration of aback-illuminated semiconductor photodetector according to a fourthmodification of the present embodiment.

FIG. 20 is a plan view illustrating a configuration of aback-illuminated semiconductor photodetector according to a fifthmodification of the present embodiment.

FIG. 21 is a plan view illustrating a configuration of aback-illuminated semiconductor photodetector according to a sixthmodification of the present embodiment.

FIG. 22 is a view illustrating a cross-sectional configuration of aback-illuminated semiconductor photodetector according to a seventhmodification of the present embodiment.

FIG. 23 is a view illustrating a cross-sectional configuration of onepixel.

FIG. 24A, 24B and 24C are schematic diagrams illustrating an example ofa manufacturing process of the back-illuminated semiconductorphotodetector according to the seventh modification.

FIG. 25A and 25B are schematic diagrams illustrating an example of themanufacturing process of the back-illuminated semiconductorphotodetector according to the seventh modification.

DESCRIPTION OF EMBODIMENT

Embodiments of the present invention will be hereinafter described indetail with reference to the accompanying drawings. In the description,the same reference numerals are used for the same elements or elementshaving the same functions, and redundant descriptions thereabout areomitted.

A configuration of a back-illuminated semiconductor photodetector 1according to the present embodiment will be described with reference toFIGS. 1 to 6. FIG. 1 is a plan view of the back-illuminatedsemiconductor photodetector according to the present embodiment. FIG. 2is a view illustrating a cross-sectional configuration of theback-illuminated semiconductor photodetector according to the presentembodiment. FIG. 3 is a plan view illustrating a configuration of theback-illuminated semiconductor photodetector according to the presentembodiment. FIGS. 4 and 5 are SEM images of a textured surface observed.FIG. 6 is a view illustrating a cross-sectional configuration of onepixel. In FIG. 6, hatching for indicating a cross section is omitted.

As illustrated in FIGS. 1 and 2, the semiconductor photodetector 1includes a semiconductor substrate 11. The semiconductor substrate 11 isa substrate made of silicon (Si). The semiconductor substrate 11includes a main surface 11 a and a main surface 11 b opposing eachother. The main surface 11 a is a light incident surface of thesemiconductor substrate 11. The main surface 11 a is a back surface, andthe main surface 11 b is a front surface. For example, the semiconductorsubstrate 11 has a polygonal shape in a plan view. In the presentembodiment, the semiconductor substrate 11 has a rectangular shape inthe plan view. For example, the semiconductor substrate 11 has athickness of 150 μm. For example, a thickness direction of thesemiconductor substrate 11 is a direction parallel to a Z axis. In thepresent embodiment, the thickness direction of the semiconductorsubstrate 11 coincides with a direction in which the main surface 11 aand the main surface 11 b oppose each other. The thickness direction ofthe semiconductor substrate 11 coincides with a direction orthogonal tothe semiconductor substrate 11, a direction orthogonal to the mainsurface 11 a, and a direction orthogonal to the main surface 11 b.

The semiconductor substrate 11 includes a semiconductor region 13 of afirst conductivity type, a plurality of semiconductor regions 15 of asecond conductivity type, and a semiconductor region 16 of the firstconductivity type. The semiconductor substrate 11 includes the pluralityof semiconductor regions 15 in a side of the main surface 11 b. Thesemiconductor substrate 11 includes the plurality of semiconductorregions 15 provided in the side of the main surface 11 b. Thesemiconductor substrate 11 includes the semiconductor region 16 in aside of the main surface 11 a. The semiconductor substrate 11 includesthe semiconductor region 16 provided in the side of the main surface 11a. The semiconductor region 16 functions as an accumulation layer. Forexample, the first conductivity type is n-type. For example, the secondconductivity type is p-type. In a case of the semiconductor substrate 11made of Si, p-type impurities include Group 13 elements, for example,and n-type impurities include Group 15 elements, for example. Forexample, the p-type impurities are boron (B). For example, the n-typeimpurities are nitrogen (N), phosphorus (P), or arsenic (As). The firstconductivity type may be p-type, and the second conductivity type may ben-type.

The semiconductor region 13 has low impurity concentration. Thesemiconductor regions 15 and 16 have high impurity concentration. Thesemiconductor regions 15 and 16 have higher impurity concentration thanthat of the semiconductor region 13. For example, the impurityconcentration of the semiconductor region 13 is 5×10¹² cm⁻³. Forexample, the impurity concentration of the semiconductor region 15 is1×10¹⁹ cm⁻³. For example, the impurity concentration of thesemiconductor region 16 is 1×10¹⁵ cm⁻³. For example, the semiconductorregion 15 has a maximum thickness of 5 μm. For example, thesemiconductor region 16 has a thickness of 1 μm.

The plurality of semiconductor regions 15 are two-dimensionallydistributed when viewed in a direction orthogonal to the semiconductorsubstrate 11. In the present embodiment, the plurality of semiconductorregions 15 are distributed in a first direction and a second directionorthogonal to each other. The plurality of semiconductor regions 15 aredistributed in M rows by N columns. Each of M and N is an integer of 2or more. For example, the first direction is a direction parallel to anX axis. For example, the second direction is a direction parallel to a Yaxis. For example, each of the semiconductor region 15 has a polygonalshape when viewed in the direction orthogonal to the semiconductorsubstrate 11. In the present embodiment, each of the semiconductorregions 15 has a rectangular shape. Each of the semiconductor regions 15may have a circular shape when viewed in the direction orthogonal to thesemiconductor substrate 11. In the present embodiment, the onesemiconductor region 15 constitutes one pixel. The semiconductorphotodetector 1 includes a plurality of pixels two-dimensionallydistributed. The semiconductor region 13 and each of the semiconductorregions 15 constitute a pn junction. The pn junction is formed at aboundary between the semiconductor region 13 and each of thesemiconductor regions 15. In each pixel, a region including thesemiconductor region 15 and the pn junction corresponds to aphotosensitive region. The rectangular shape includes a shape withchamfered corners, and a shape with rounded corners.

The semiconductor substrate 11 includes a semiconductor region 14 of thefirst conductivity type. The semiconductor substrate 11 includes thesemiconductor region 14 in the side of the main surface 11 b. Thesemiconductor substrate 11 includes the semiconductor region 14 providedin the side of the main surface 11 b. The semiconductor region 14 has aframe shape when viewed in the direction orthogonal to the main surface11 b. The semiconductor region 14 is provided along an edge of the mainsurface 11 b in such a manner as to surround the region where theplurality of semiconductor regions 15 are distributed when viewed in thedirection orthogonal to the main surface 11 b. The semiconductor region14 functions as a channel stop layer to stop a depletion layer beforereaching a side surface of the semiconductor substrate 11.

Each of the semiconductor regions 15 includes a region 17 including atextured surface TS, and a region 19 not including the textured surfaceTS. The textured surface TS is a surface that includes fine protrusionsand recesses as illustrated in FIGS. 4 and 5. The region 17 is a regionwhere fine protrusions and recesses are formed on the surface. Theentire surface of the region 17 includes fine protrusions and recesses.The entire surface of the region 17 includes the textured surface TS.The region 17 of the semiconductor region 15 is provided along thetextured surface TS. A boundary interface between the region 17 and thesemiconductor region 13 includes protrusions and recesses correspondingto the protrusions and recesses of the textured surface TS. For example,the boundary interface between the region 17 and the semiconductorregion 13 includes protrusions and recesses that are more gradual thanthe protrusions and recesses of the textured surface TS.

For example, the textured surface TS is formed with wet etching. Thetextured surface TS may be formed with dry etching or laser irradiation.The region that includes a surface constituted by the textured surfaceTS corresponds to a textured region. The textured surface TS illustratedin FIG. 4 is formed with wet etching. The textured surface TSillustrated in FIG. 5 is formed with dry etching. In FIG. 3, the regioncorresponding to the textured surface TS is hatched to help easyunderstanding of the region constituted by the textured surface TS.

The protrusions and recesses of the textured surface TS are irregularlyformed. The irregularity of the protrusions and recesses of the texturedsurface TS refers to at least either a state where intervals of tops ofthe protrusions and recesses irregularly change, or a state where heightdifferences of the protrusions and recesses irregularly change. In thepresent embodiment, the intervals of the tops of the protrusions andrecesses irregularly change, and also the height differences of theprotrusions and recesses irregularly change. For example, an interval ofthe tops of the protrusions and recesses of the textured surface TSranges from 0.1 to 1.0 μm. For example, a height difference of theprotrusions and recesses of the textured surface TS ranges from 0.5 to1.5 μm. The protrusions and recesses of the textured surface TS may beregularly formed.

As illustrated in FIG. 3, the region 17 is located inside the region 19when viewed in the direction orthogonal to the semiconductor substrate11. In the present embodiment, an entire edge of the region 17 issurrounded by the region 19 when viewed in the direction orthogonal tothe semiconductor substrate 11. The region 19 includes a flat surface.The region 19 is provided along the main surface 11 b. The region 19includes two regions 19 a and 19 b that are continuous with each other.The region 19 a is located along the edge of the semiconductor region15. The region 19 b is located at one corner of the semiconductor region15. The surface of the region 19 a and the surface of the region 19 bare located in the same plane. The region 17 has a shape produced bycutting out a rectangular portion from one corner of the rectangularshape when viewed in the direction orthogonal to the semiconductorsubstrate 11. As illustrated in FIG. 3, the region 17 and the region 19b are adjacent to each other in a direction crossing the first directionand the second direction when viewed in the direction orthogonal to thesemiconductor substrate 11.

As illustrated in FIG. 6, the textured surface TS is located toward themain surface 11 a in comparison to the surface of the region 19 (regions19 a and 19 b) in the thickness direction of the semiconductor substrate11. That is, the textured surface TS is located toward the main surface11 a in comparison to a virtual plane VP including the surface of theregion 19 (regions 19 a and 19 b). The main surface 11 b is recessed inthe region 17. A step is formed by the textured surface TS and thesurface of the region 19. An edge region TSa of the textured surface TSof the region 17 is continuous with the surface of the region 19(regions 19 a, 19 b), and is inclined to the thickness direction of thesemiconductor substrate 11. In the present embodiment, the edge regionTSa is inclined such that the thickness of the region 17 in the edgeregion TSa gradually increases from the region 17 toward the region 19.

The semiconductor photodetector 1 includes a plurality of insulatingfilms 21, 23, and 25, a plurality of pad electrodes 31, a plurality ofUBMs (under-bump metals) 33, and a plurality of bump electrodes 35. Inthe present embodiment, the semiconductor photodetector 1 includes theone pad electrode 31, the one UBM 33, and the one bump electrode 35 foreach of the semiconductor regions 15. The semiconductor photodetector 1includes an electrode (not illustrated) electrically connected to thesemiconductor region 14. The electrode electrically connected to thesemiconductor region 14 is disposed on the side of the main surface 11b.

The insulating film 21 is disposed on the main surface 11 a of thesemiconductor substrate 11. The insulating film 21 is formed on the mainsurface 11 a. For example, the insulating film 21 is an oxide film. Inthe present embodiment, the insulating film 21 is made of silicon oxide(SiO₂). For example, the insulating film 21 is a silicon thermal oxidefilm. The insulating film 21 may be made of silicon nitride (SiN). Inthis case, the insulating film 21 is formed with plasma CVD(Plasma-enhanced Chemical Vapor Deposition), for example. The insulatingfilm 21 functions as an antireflective film. For example, the insulatingfilm 21 has a thickness of 0.1 μm.

The insulating film 23 is disposed on the main surface 11 b of thesemiconductor substrate 11. The insulating film 23 is formed on the mainsurface 11 b. For example, the insulating film 23 is an oxide film. Inthe present embodiment, the insulating film 21 is made of silicon oxide.For example, the insulating film 23 is a silicon thermal oxide film. Theinsulating film 23 covers the surfaces of the respective semiconductorregions 15. The insulating film 23 directly covers the entire texturedsurfaces TS. The insulating film 23 is in contact with the main surface11 b (textured surfaces TS). The insulating film 23 may be made ofsilicon nitride. In this case, the insulating film 23 is formed with lowCVD (Low-pressure Chemical Vapor Deposition). The insulating film 23 maybe made of aluminum oxide (Al₂O₃). In this case, the insulating film 23is formed with ALD (Atomic Layer Deposition). For example, theinsulating film 23 has a thickness of 0.2 μm.

The insulating film 25 is disposed on the main surface 11 b of thesemiconductor substrate 11. The insulating film 25 is formed on theinsulating film 23. The insulating film 25 is in contact with theinsulating film 23. For example, the insulating film 25 is a nitridefilm. In the present embodiment, the insulating film 25 is made ofsilicon nitride. The insulating film 23 is located between thesemiconductor substrate 11 and the insulating film 25. The insulatingfilm 25 is indirectly disposed on the semiconductor substrate 11. Theinsulating film 25 indirectly covers the surfaces of the respectivesemiconductor regions 15. The insulating film 25 directly covers aregion included in the insulating film 23 and corresponding to theregions 17. The insulating film 25 indirectly covers the entire texturedsurfaces TS. The insulating film 25 may be made of silicon oxide. Inthis case, the insulating film 25 is formed with plasma CVD, forexample. The insulating film 25 functions as a passivation film. Forexample, the insulating film 25 has a thickness ranging from 0.1 to 0.4μm.

The pad electrode 31 is disposed on the region 19. In the presentembodiment, the pad electrode 31 is disposed on the region 19 b. The padelectrode 31 is formed on the region 19 b and the insulating film 23.The pad electrode 31 is connected to the region 19 b via a contact holeH1 formed in the insulating film 23. The pad electrode 31 is in contactwith the region 19 and the insulating film 23. The pad electrode 31 isdirectly disposed on the region 19 b. The pad electrode 31 is in contactwith the insulating film 25. The insulating film 25 covers peripheraledges of the pad electrodes 31. The pad electrode 31 is made of aconductive material. For example, the pad electrode 31 is made ofaluminum (Al). In this case, the pad electrode 31 is formed withsputtering or vapor deposition.

As illustrated in FIG. 3, the pad electrode 31 includes two electroderegions 31 a and 31 b. In the present embodiment, the pad electrode 31is constituted by the two electrode regions 31 a and 31 b. The electroderegion 31 a is disposed on the region 19. In the present embodiment, theelectrode region 31 a is disposed on the region 19 b. The electroderegion 31 a is in contact with the region 19 b. The electrode region 31a is directly disposed on the region 19 b. The electrode region 31 b isdisposed on at least a part of a region included in the insulating film23 and corresponding to the region 17. The electrode region 31 b isdisposed on the region 17 such that the insulating film 23 is locatedbetween the region 17 and the electrode region 31 b. The electroderegion 31 b is continuous with the electrode region 31 a. The padelectrode 31 overlaps with an entire boundary between the region 17 andthe region 19 b when viewed in the direction orthogonal to thesemiconductor substrate 11. In the present embodiment, the electroderegion 31 b overlaps with the edge region TSa that is continuous withthe region 19 b when viewed in the direction orthogonal to thesemiconductor substrate 11. The electrode region 31 b is indirectlydisposed on the edge region TSa. FIG. 3 does not illustrate theinsulating films 23 and 25.

The UBM 33 is disposed on the region 19. In the present embodiment, theUBM 33 is disposed on the region 19 b. The UBM 33 is formed on theregion 19 b and the insulating film 25. The UBM 33 is connected to thepad electrode 31 via a contact hole H2 formed in the insulating film 25.The UBM 33 is in contact with the pad electrode 31. The UBM 33 is incontact with the insulating film 25. The UBM 33 is made of a materialhaving excellent electrical and physical connection with the bumpelectrode 35. For example, the UBM 33 is a laminated body constituted bya layer made of titanium (Ti) and a layer made of platinum (Pt). Forexample, the UBM 33 is formed with multilayer vapor deposition.

The bump electrode 35 is disposed on the region 19. In the presentembodiment, the bump electrode 35 is disposed on the region 19 b. Thebump electrode 35 is formed on the UBM 33. The bump electrode 35 is incontact with the UBM 33. The UBM 33 is located between the pad electrode31 and the bump electrode 35. The bump electrode 35 is indirectlydisposed on the region 19. The bump electrode 35 is indirectly disposedon the pad electrode 31. The bump electrode 35 is electrically connectedto the region 19 b (semiconductor region 15) via the UBM 33 and the padelectrode 31. The bump electrode 35 is made of a solder material. Forexample, the bump electrode 35 is made of indium (In). For example, thebump electrode 35 is formed with vapor deposition.

In the semiconductor photodetector 1, the semiconductor region 13 iscompletely depleted due to applying a bias voltage. That is, a depletionlayer extending from the semiconductor region 15 reaches thesemiconductor region 13. The semiconductor region 13 need not becompletely depleted.

Next, an example of a manufacturing process of the semiconductorphotodetector 1 will be described with reference to FIGS. 7A to 9C. Eachof FIGS. 7A to 9C is a schematic diagram illustrating an example of themanufacturing process of the back-illuminated semiconductorphotodetector according to the present embodiment. In FIGS. 7A to 9C,hatching for indicating a cross section is omitted.

As illustrated in FIG. 7A, the n-type semiconductor substrate 11 isprovided. An oxide film 51 is formed on the main surface 11 a, while anoxide film 53 is formed on main surface 11 b. For example, the oxidefilms 51 and 53 are formed due to heating the semiconductor substrate 11in an oxygen atmosphere. In a state illustrated in FIG. 7A, thesemiconductor substrate 11 is constituted by the semiconductor region13, and does not include the semiconductor regions 15 and thesemiconductor region 16. That is, the semiconductor substrate 11including the semiconductor region 13 is provided. The semiconductorsubstrate 11 includes a plurality of planned regions PR where theplurality of semiconductor regions 15 are going to be formed, in a sideof the main surface 11 b. In FIGS. 7A to 9C, only one planned region PRis illustrated.

As illustrated in FIG. 7B, the plurality of semiconductor regions 15 ₁and the semiconductor region 16 are formed on the semiconductorsubstrate 11.

The semiconductor regions 15 ₁ are formed in a following manner.Openings 53 a are formed in the oxide film 53 due to patterning theoxide film 53. The openings 53 a have a rectangular shape. P-typeimpurities are doped to the semiconductor substrate 11 from the mainsurface 11 b via the opening 53 a of the oxide film 53. The doped p-typeimpurities diffuse into the semiconductor substrate 11 due to a hightemperature heat treatment. The semiconductor regions 15 are constitutedby the high-concentration p-type impurities diffused from the mainsurface 11 b. An oxide film 55 is formed on the semiconductor region 15₁ due to the above high temperature heat treatment (see FIG. 7C.

The semiconductor region 16 is formed in a following manner. N-typeimpurities are doped to the semiconductor substrate 11 from the mainsurface 11 a. The doped n-type impurities diffuse into the semiconductorsubstrate 11 due to the above high temperature heat treatment. Thesemiconductor region 16 is constituted by the high-concentration n-typeimpurities diffused from the main surface 11 a.

As illustrated in FIG. 7C, the contact holes H1 are formed in the oxidefilm 55 due to patterning the oxide film 55. After the contact holes H1are formed, a silicon nitride film 57 is formed on the oxide films 51and 55. The silicon nitride film 57 is formed with low pressure CVD, forexample.

As illustrated in FIG. 8A, the silicon nitride film 57 formed on theoxide film 55, and the oxide film 55 are patterned, and the opening 59is formed in the semiconductor region 15 ₁ at a position correspondingto the region 17. The opening 59 is formed with dry etching, forexample.

As illustrated in FIG. 8B, the textured surface TS is formed in a regionincluded in the semiconductor region 15 ₁and exposed through the opening59. That is, a plurality of textured regions are formed on surfacesincluded in the plurality of planned regions PR described above in themain surface 11 b. The textured region is a region that includes asurface constituting the textured surface TS. For example, the texturedsurface TS is formed with wet etching as described above. The regionincluded in the semiconductor region 15 ₁ and exposed from the opening59 is removed due to forming the textured surface TS. The regionincluded in the semiconductor region 15 ₁ and exposed from the opening59 need not be completely removed, but a part of the region exposedthrough the opening 59 may be left. In FIG. 8B and subsequent figures, across-hatched region is a region where the textured surface TS isformed.

As illustrated in FIG. 8C, a plurality of semiconductor regions 15 ₂ areformed on the semiconductor substrate 11. The semiconductor region 15 ₂is formed along the textured surface TS. That is, the semiconductorregions 15 ₂ is formed along a surface shape of the textured region.Each of the semiconductor regions 15 ₂ is formed in the correspondingplanned region PR of the plurality of planned regions PR. Thesemiconductor regions 15 ₂ are formed with the same process as theprocess described above of forming the semiconductor regions 15 ₁. Thesemiconductor regions 15 ₂ are constituted by high-concentration p-typeimpurities diffused from the main surface 11 b. The p-type impuritiesalso diffuse in the direction orthogonal to the thickness direction ofthe semiconductor substrate 11. Therefore, the semiconductor region 15 ₂is formed continuously with the semiconductor region 15 ₁. Thesemiconductor region 15 ₂ and the semiconductor region 15 ₁ areintegrated to constitute the semiconductor region 15. The semiconductorregion 15 ₂ constitutes the region 17. The semiconductor region 15 ₁constitutes the region 19. That is, the plurality of semiconductorregions 15 are formed in the semiconductor substrate 11 with thisprocess. The oxide film 61 is formed on the textured surface TS due to ahigh temperature heat treatment for forming the semiconductor regions 15₂. The oxide films 53 and 61 constitute the insulating film 23.

As illustrated in FIG. 9A, the silicon nitride film 57 is removed fromthe upper side of the oxide film 51 and the insulating film 23 (oxidefilms 53 and 61). The semiconductor region 15 is exposed through thecontact hole H1 due to removing the silicon nitride film 57. Thereafter,the pad electrode 31 is formed on the region included in thesemiconductor region 15 and exposed through the contact hole H1. The padelectrode 31 is also formed to be located on a region included in theinsulating film 23 and located around the contact hole H1. The oxidefilm 51 constitutes the insulating film 21.

After the insulating film 25 is formed on the insulating film 23, thecontact holes H2 are formed in the insulating film 25 due to patterningthe insulating film 25 as illustrated in FIG. 9B. A part of the padelectrode 31 is exposed due to forming the contact hole H2.

As illustrated in FIG. 9C, the UBM 33 is formed on a region included inthe pad electrode 31 and exposed through the contact hole H2. The UBM 33is also formed to be located on a region included in the insulating film25 and located around the contact hole H2. That is, the UBM 33 is alsoformed to be indirectly disposed on the region 19. Thereafter, the bumpelectrode 35 is formed on the UBM 33. The semiconductor photodetector 1is obtained with these processes.

The configuration of the semiconductor photodetector 1 will beredescribed with reference to FIG. 6.

As illustrated in FIG. 6, a thickness TH1 of the region 17 at a deepestposition of the recesses of the textured surface TS is smaller than adistance D1 between the surface of the region 19 (region 19 b) and thedeepest position in the thickness direction of the semiconductorsubstrate 11. For example, the deepest position is a deepest position ofa deepest recess in all of the recesses. The deepest position may be adeepest position of any one of all of the recesses. The deepest positionmay be an average position of the deepest positions of all of therecesses.

For example, impurity concentration of the region 17 (semiconductorregion 15 ₂) included in the semiconductor region 15 changes with adepth from the front surfaces as illustrated in FIG. 10. That is, theimpurity concentration of the semiconductor regions 15 ₂ changes with adistance from the textured surfaces TS in the thickness direction of thesemiconductor substrate 11, for example. FIG. 10 is a chart illustratinga distribution of the impurity concentration. FIG. 10 illustrates thetextured surface TS and an interface between the region 17 and thesemiconductor region 13 flat, for convenience of illustration. Actually,however, the textured surface TS and the interface between the region 17and the semiconductor region 13 exhibit fine protrusions and recesses asdescribed above.

The impurity concentration of the semiconductor region 15 is kept highup to a position of a predetermined depth, and gradually decreases fromthe position of the predetermined depth toward the main surface 11 a.The semiconductor region 15 includes a region R1 that is located closerto the main surface 11 b, and a region R2 that is located toward themain surface 11 a in comparison to the region R1 is, on the basis of thedistribution of the impurity concentration. The region R1 and the regionR2 are continuous with each other. The region R1 is a high impurityconcentration region. The region R2 is a transition region where theimpurity concentration gradually decreases from the impurityconcentration of the region R1. In the semiconductor region 15 ₂ (region17), an occupancy of the region R2 is higher than an occupancy of theregion R1. In the present embodiment, a deepest position of the recessesof the textured surface TS is separated from a region where the impurityconcentration of the semiconductor regions 15 begins to decrease by athickness of the region R1. In the present embodiment, the predetermineddepth is approximately 0.45 μm, for example.

For example, a thickness of the semiconductor region 15 (regions 17 and19) is defined by a distance between the front surface and a depth atwhich the impurity concentration of the semiconductor region 15 becomesequal to the impurity concentration of the semiconductor region 16. Thisdistance also corresponds to the distance of the semiconductor substrate11 in the thickness direction. In this case, the thickness TH1 isdefined by a distance between the deepest position of the recesses ofthe textured surface TS and the depth at which the impurityconcentration of the region 17 becomes equal to the impurityconcentration of the semiconductor region 16. For example, the deepestposition of the recesses is a deepest position of the deepest recess ofall of the recesses. In this case, the thickness TH1 indicates a minimumvalue of the thickness of the region 17. For example, the deepestposition of the recesses may be a deepest position of the shallowestrecess of all of the recesses. In this case, the thickness TH1 indicatesa maximum value of the thickness of the region 17. For example, thedeepest position of the recesses may be an average position of thedeepest positions of all the recesses. In this case, the thickness TH1indicates an average value of the thickness of the region 17. Forexample, the thickness TH1 ranges from 0.1 to 1.0 μm.

For example, the thickness of the semiconductor region 15 (regions 17and 19) may be defined by a distance between the front surface and aposition where the region R2 ends in the thickness direction of thesemiconductor substrate 11. As can be seen from FIG. 10, the positionwhere the region R2 ends is a position where the decrease of theimpurity concentration ends. In this case, the thickness TH1 is definedby a distance between the deepest position of the recesses of thetextured surface TS and the position where the region R2 ends.

The distance D1 is a depth of the recesses of the textured surface TS.In a case where the deepest position is the deepest position of thedeepest recess, the distance D1 is a maximum value of the depths of therecesses of the textured surface TS. In a case where the deepestposition is the deepest position of the shallowest recess, the distanceD1 is a minimum value of the depths of the recesses of the texturedsurface TS. In a case where the deepest position is the average positionof the deepest positions of all the recesses, the distance D1 is anaverage depth of the recesses of the textured surface TS. For example,the distance D1 ranges from 1.0 to 2.5 μm.

The thickness TH2 of the region 19 (region 19 b) in the thicknessdirection of the semiconductor substrate 11 is equal to the thicknessTH3 of the region 17 in the thickness direction of the semiconductorsubstrate 11. As described above, the region 17 is formed along thetextured surface TS. Therefore, the thickness TH3 tends not to change incorrespondence with the protrusions and recesses of the textured surfaceTS. In the present embodiment, the thickness TH3 is approximatelyconstant, for example. The thickness TH1 of the region 17 at the deepestposition of the recesses of the textured surface TS is equal to each ofthe thickness TH2 and the thickness TH3. For example, the thickness TH1,the thickness TH2, and the thickness TH3 are 0.5 μm.

Next, a configuration of an electronic component device ED including thesemiconductor photodetector 1 will be described with reference to FIG.11. FIG. 11 is a view illustrating a cross-sectional configuration of anelectronic component device that includes the back-illuminatedsemiconductor photodetector according to the present embodiment.

The electronic component device ED includes the semiconductorphotodetector 1, an electronic component EC on which the semiconductorphotodetector 1 is mounted, and a resin layer RL. For example, theelectronic component EC includes a wiring board or an ASIC (ApplicationSpecific Integrated Circuit).

The electronic component EC includes a plurality of pad electrodes 71, aplurality of UBMs 73, and a plurality of bump electrodes 75. Theplurality of pad electrodes 71, the plurality of UBMs 73, and theplurality of bump electrodes 75 are disposed at positions correspondingto the plurality of bump electrodes 35 included in the semiconductorphotodetector 1. The semiconductor photodetector 1 is mounted on theelectronic component EC due to joining the bump electrodes 35 and thebump electrodes 75 associated with each other. The electrodeelectrically connected to the semiconductor region 14 is also joined toa bump electrode (not illustrated) of the electronic component EC.

The resin layer RL is disposed between the semiconductor photodetector 1and the electronic component EC. The resin layer RL functions as anunderfill layer. The resin layer RL is produced due to curing a resinmaterial filled in a space formed between the semiconductorphotodetector 1 and the electronic component EC. For example, the resinlayer RL contains epoxy resin, urethane resin, silicone resin, oracrylic resin.

As described above, in the semiconductor photodetector 1, the region 17of the semiconductor region 15 includes the textured surface TS. Lightin a long wavelength range has a small absorption coefficient ascompared with light in a short wavelength range. Therefore, light in along wavelength range that is incident on the semiconductor substrate 11from the main surface 11 a travels in the semiconductor substrate 11 andreaches the textured surface TS. The light having reached the texturedsurface TS is reflected or diffused at the textured surface TS, andfurther travels in the semiconductor substrate 11. The light in the longwavelength range travels a long distance within the semiconductorsubstrate 11, and thus is absorbed by the semiconductor substrate 11.Consequently, the semiconductor photodetector 1 improves spectralsensitivity characteristics in the long wavelength range.

Carriers generated due to absorption of light by the semiconductorsubstrate 11 may be recombined in the semiconductor regions 15. Carriersrecombined in the semiconductor regions 15 do not contribute todetection sensitivity. Therefore, the spectral sensitivitycharacteristics may deteriorate. In a configuration where thesemiconductor region 15 has a large thickness, recombination of carriersin the semiconductor regions 15 tends to occur as compared with in aconfiguration where the semiconductor region 15 has a small thickness.That is, in a configuration where a distance between the surface of thesemiconductor region 15 and the pn junction is long, recombination ofcarriers in the semiconductor regions 15 tends to occur as compared within a configuration where the distance between the surface of thesemiconductor region 15 and the pn junction is short.

In the manufacturing process described above, the plurality ofsemiconductor regions 15 (the plurality of semiconductor regions 15 ₂)are formed in the plurality of planned regions PR after the texturedregion is formed on the main surface 11 b. In a process where thetextured regions (textured surfaces TS) are formed after forming theplurality of semiconductor regions 15, the thickness of each of thesemiconductor regions 15 inevitably increases to reliably prevent thetexture regions from reaching the pn junctions. Therefore, in theprocess of forming the plurality of semiconductor regions 15 afterforming the textured regions, the thickness of each of the semiconductorregions 15 can be reduced as compared with in the process of forming thetextured regions after forming the plurality of semiconductor regions15. Consequently, the semiconductor photodetector 1 can further improvethe spectral sensitivity characteristics in the long wavelength range.

In a case where the textured region (textured surface TS) is formed onthe semiconductor substrate 11, those skilled in the art estimate thatthe textured region may have structural defects. Therefore, thoseskilled in the art are hesitant to form the semiconductor region 15(semiconductor region 15 ₂) after forming the textured region. Incontrast, in the present embodiment, the plurality of semiconductorregions 15 are intentionally formed after forming the textured region tofurther improve the spectral sensitivity characteristics in the longwavelength range.

In the manufacturing process described above, the semiconductor region15 ₂ (region 17) is formed along the surface shape of the texturedregion. In this case, the thickness of the semiconductor region 15 ₂(region 17) can be further reduced. Therefore, the semiconductorphotodetector 1 can further improve the spectral sensitivitycharacteristics in the long wavelength range with reliability.

In the manufacturing process described above, the semiconductor regions15 ₂ (regions 17) are formed due to adding p-type impurities into theplanned region PR. In this case, the semiconductor regions 15 ₂ areeasily formed due to using an existing method.

In the manufacturing process described above, the textured surface TS isprovided for the semiconductor region 15.

Light having reached the surface of the textured surface TS is reflectedor scattered by the textured surface TS as described above. The lightreflected or scattered by the textured surface TS travels in variousdirections crossing the thickness direction of the semiconductorsubstrate 11 as compared with light reflected at a flat surface.Therefore, the light reflected or diffused at the textured surface TSmay travel toward adjacent pixels and cause crosstalk between thepixels. Crosstalk causes noise.

In the semiconductor photodetector 1, the textured surface TS isprovided for the semiconductor region 15. The textured surface TS is notprovided in regions of the main surface 11 b other than thesemiconductor regions 15. The configuration where the textured surfaceTS is provided for the semiconductor region 15 regulates generation ofcrosstalk as compared with a configuration where the textured surface TSis provided throughout the main surface 11 b. Therefore, thesemiconductor photodetector 1 reduces generation of crosstalk.

In the semiconductor photodetector 1, the thickness TH1 is smaller thanthe distance D1. In the semiconductor photodetector 1, the distancebetween the textured surface TS and the pn junction is short as comparedwith in a configuration where the thickness TH1 is equal to or largerthan the distance D1. Therefore, recombination of carriers generated bylight incident on the semiconductor substrate 11 decreases in thesemiconductor regions 15. Consequently, the semiconductor photodetector1 further improves the spectral sensitivity characteristics in the longwavelength range.

In a case where stress acts on the semiconductor substrate 11, carriersthat are not attributable to incidence of light may be generated.Carriers that are not attributable to incidence of light produce darkcurrents. Stress tends to act on the region 19 as compared with on theregion 17, and therefore carriers that are not attributable to incidenceof light tends to be generated in the region 19.

In a configuration where the thickness TH2 is larger than the thicknessTH3, recombination of carriers that are not attributable to incidence oflight tends to be caused in the region 19 as compared with aconfiguration where the thickness TH2 is equal to or smaller than thethickness TH3. Therefore, the semiconductor photodetector with theconfiguration where the thickness TH2 is larger than the thickness TH3reduces generation of the dark currents.

In the semiconductor photodetector 1, the pad electrode 31 is in contactwith the region 19 (region 19 b). In a case where the pad electrodes 31and the semiconductor substrate 11 are in contact with each other, amaterial (Al) forming the pad electrodes 31 and a material (Si) formingthe semiconductor substrate 11 are alloyed with each other, so that analloy spike may be produced in the semiconductor substrate 11. The alloyspike having reached the pn junction increases leakage currents.

In a configuration where the thickness TH2 is larger than the thicknessTH3, the alloy spike tends not to reach the pn junction as compared within a configuration where the thickness TH2 is equal to or smaller thanthe thickness TH3. Therefore, the semiconductor photodetector with theconfiguration where the thickness TH2 is larger than the thickness TH3reduces an increase in leakage currents.

In the semiconductor photodetector 1, the textured surface TS is locatedtoward the main surface 11 a in comparison to the surface of the region19 in the thickness direction of the semiconductor substrate 11. Thatis, the textured surface TS is located toward the main surface 11 a incomparison to the virtual plane VP. In this case, stress tends not toact on the region 17. Therefore, generation of carriers that are notattributable to incidence of light is reduced in the region 17.Consequently, the semiconductor photodetector 1 reduces generation ofthe dark currents.

In the semiconductor photodetector 1, the distance between the texturedsurface TS and the pn junction further decreases in a case where thetextured surface TS is formed in the semiconductor region 15 as in themanufacturing process described above. Therefore, the semiconductorphotodetector 1 further improves the spectral sensitivitycharacteristics in the long wavelength range.

The semiconductor photodetector 1 is mounted on the electronic componentEC via the bump electrode 35. Therefore, stress acts on the region 19(region 19 b) when the semiconductor photodetector 1 is mounted on theelectronic component EC. Since the textured surface TS is located towardthe main surface 11 a in comparison to the virtual plane VP, stresstends not to act on the region 17 even in a case where the semiconductorphotodetector 1 is mounted on the electronic component EC. Therefore,generation of carriers that are not attributable to incidence of lightis reduced in the region 17. The semiconductor photodetector 1 furtherreduces generation of the dark currents.

If the bump electrode 35 (or the bump electrode 75) is crushed at thetime when the semiconductor photodetector 1 is mounted on the electroniccomponent EC, the crushed bump electrode 35 (or the bump electrode 75)may physically interfere with a portion of the semiconductorphotodetector 1 other than the bump electrode 35. For example, theportion other than the bump electrode 35 includes a wiring conductor orthe textured surface TS. In a case where the bump electrode 35 (or thebump electrode 75) physically interferes with the wiring conductor, thebump electrode 35 (or the bump electrode 75) and the wiring conductormay be short-circuited. In a case where the bump electrode 35 (or thebump electrode 75) physically interferes with the textured surface TS,the textured surface TS may be physically damaged, so that the spectralsensitivity characteristics in the long wavelength range may beadversely affected.

In the semiconductor photodetector 1, the textured surface TS is locatedtoward the main surface 11 a in comparison to the virtual plane VP. Thestep is formed by the textured surface TS and the surface of the region19. Therefore, the crushed bump electrode 35 (or the bump electrode 75)tends not to interfere with the portion of the semiconductorphotodetector 1 other than the bump electrode 35 when the semiconductorphotodetector 1 is mounted on the electronic component EC. Thesemiconductor photodetector 1 achieves reduction of generation of ashort circuit between the bump electrodes 35 (or the bump electrodes 75)and the wiring conductor, and reduction of adverse effects on thespectral sensitivity characteristics in the long wavelength range.

A device that forms the bump electrodes 35 may physically interfere withthe textured surface TS when forming the bump electrodes 35. In a casewhere the device that forms the bump electrodes 35 physically interfereswith the textured surface TS, the textured surface TS may be physicallydamaged, so that the spectral sensitivity characteristics in the longwavelength range may be adversely affected.

In the semiconductor photodetector 1, the textured surface TS is locatedtoward the main surface 11 a in comparison to the virtual plane VP.Therefore, the device that forms the bump electrodes 35 tends not tophysically interfere with the textured surface TS. The semiconductorphotodetector 1 reduces adverse effects on the spectral sensitivitycharacteristics in the long wavelength range when forming the bumpelectrodes 35.

In the semiconductor photodetector 1, the edge region TSa of thetextured surface TS is continuous with the surface of the region 19(regions 19 a, 19 b), and is inclined to the thickness direction of thesemiconductor substrate 11. In a case where the textured surface TS islocated toward the main surface 11 a in comparison to the virtual planeVP, stress tends to act on the region 19 further.

In the semiconductor photodetector 1, the stress acting on the region 19tends to be dispersed as compared with in a configuration where the edgeregion TSa is parallel to the thickness direction of the semiconductorsubstrate. Therefore, even in a case where stress acts on the region 19,concentration of the stress on the region 19 decreases. Thesemiconductor photodetector 1 reduces generation of carriers that arenot attributable to incidence of light. Consequently, the semiconductorphotodetector 1 further reduces generation of the dark currents.

In the semiconductor photodetector 1, the region 19 (regions 19 a, 19 b)does not include the textured surface TS. In the semiconductorphotodetector 1, the pad electrode 31 is easily formed on the region 19(region 19 b) as compared with in a configuration where the region 19includes the textured surface TS.

In the semiconductor photodetector 1, the pad electrode 31 includes theelectrode region 31 a and the electrode region 31 b. The electroderegion 31 a is disposed on the region 19 (region 19 b). The electroderegion 31 b is disposed on the region 17 such that the insulating film23 is located between the electrode region 31 b and the region 17. Theelectrode region 31 a is continuous with the electrode region 31 b. Thatis, the pad electrode 31 is disposed to extend over the region 19 b andthe region 17. In this configuration, an area of the pad electrodes 31is large as compared with in a configuration where the pad electrode 31is disposed only on the region 19 b. The UBM 33 and the bump electrode35 are disposed on the pad electrode 31 having a large area. Therefore,the semiconductor photodetector 1 improves reliability and stability ofan electrical connection between the semiconductor region 15 (region 19)and the bump electrode 35.

A configuration of the textured surface TS (region 17) having a largearea improves the spectral sensitivity characteristics in the longwavelength range as compared with a configuration of the texturedsurface TS (region 17) having a small area. Therefore, to improve thespectral sensitivity characteristics in the long wavelength range, theregion 17 having a largest possible area and the region 19 (region 19 b)having a smallest possible area are required.

The pad electrode 31 contacts the region 19 b via the contact hole H1.The contact hole H1 is formed in a region included in the insulatingfilm 23 and located above the region 19 b to easily form the contacthole H1. The contact hole H1 is easily formed in the insulating film 23because the surface of the region 19 b is flat. In a case where the padelectrode 31 is formed at a position shifted from the contact hole H1,the region 19 b is exposed through the contact hole H1. In this case,breakdown voltage characteristics and reliability may deteriorate.Therefore, the area of the pad electrode 31 is set in consideration ofaccuracy of the formation position of the contact hole H1 and accuracyof the formation position of the pad electrode 31. Consequently, thearea of the pad electrode 31 inevitably increases.

In a configuration where the pad electrode 31 does not include theelectrode region 31 b, the pad electrode 31 and the region 17 do notoverlap with each other when viewed in the direction orthogonal to themain surface 11 b. In this configuration, an area of the region 19 bneeds to increase so as to secure the area of the pad electrode 31, andthe area of the region 17 is required to decrease. Therefore, theconfiguration where the pad electrode 31 does not include the electroderegion 31 b tends not to improve the spectral sensitivitycharacteristics in the long wavelength range.

In the semiconductor photodetector 1, the pad electrode 31 includes theelectrode region 31 b. That is, at least a part of the pad electrodes 31and a part of the regions 17 overlap with each other when viewed in thedirection orthogonal to the main surface 11 b. Therefore, even in a casewhere the areas of the pad electrodes 31 are secured, the semiconductorphotodetector 1 improves the spectral sensitivity characteristics in thelong wavelength range.

In the semiconductor photodetector 1, the insulating film 25 covers theperipheral edges of the pad electrodes 31. Therefore, the insulatingfilm 25 reduces separation of the pad electrodes 31. The insulating film25 reduces entrance of a material component of the bump electrodes 35from an interface between the pad electrodes 31 and the insulating film23. The insulating film 25 reduces generation of leakage currents andshort circuit.

In the semiconductor photodetector 1, the insulating film 25 covers aregion included in the insulating film 23 and corresponding to theregions 17. A laminated film constituted by the insulating film 23 andthe insulating film 25 covers the entire textured surface TS. Thelaminated film (insulating films 23, 25) can constitute a highlyreflective film in a case where thicknesses of the insulating film 23and the insulating film 25 is set to desired values. In a configurationwhere a highly reflective film is constituted by the laminated film(insulating films 23, 25), the spectral sensitivity characteristics inthe long wavelength range further improve.

The insulating film 23 is the oxide film, and the insulating film 25 isthe nitride film. Therefore, the laminated film (insulating films 23,25) can easily constitute the highly reflective film.

In a case where the insulating film 23 is the silicon thermal oxidefilm, the protrusions and recesses of the textured surface TS aresmoothed due to the heat treatment in the process of forming theinsulating film 23. In a case where the protrusions and recesses of thetextured surface TS are smoothed, a process of forming metal wiringincluding the pad electrodes 31 is easily performed.

Next, a configuration of the semiconductor photodetector 1 according toa first modification of the above embodiment will be described withreference to FIGS. 12 and 13. FIG. 12 is a view illustrating across-sectional configuration of a back-illuminated semiconductorphotodetector according to the first modification. FIG. 13 is a planview illustrating the configuration of the back-illuminatedsemiconductor photodetector according to the first modification. FIG. 13does not illustrate the insulating films 23 and 25. In FIG. 13, a regioncorresponding to the textured surface TS is hatched to help easyunderstanding of a region constituted by the textured surface TS. Thefirst modification is substantially similar or identical to theembodiment described above. However, the first modification is differentfrom the above embodiment in the configuration of the semiconductorsubstrate 11. Differences between the above embodiment and the firstmodification will be hereinafter chiefly described.

The semiconductor substrate 11 includes a semiconductor region 20 of thefirst conductivity type. The semiconductor substrate 11 includes thesemiconductor region 20 in a side of the main surface 11 b. Thesemiconductor substrate 11 includes the semiconductor region 20 providedin the side of the main surface 11 b. The semiconductor region 20 hashigh impurity concentration. For example, the semiconductor region 20has impurity concentration of 1×10¹⁸ cm⁻³. For example, thesemiconductor region 20 has a thickness of 1.5 μm. The semiconductorregion 20 has a grid shape when viewed in the direction orthogonal tothe main surface 11 b. The semiconductor region 20 is located betweenthe semiconductor regions 15 adjacent to each other in the firstdirection and between the semiconductor regions 15 adjacent to eachother in the second direction when viewed in the direction orthogonal tothe main surface 11 b. The semiconductor region 20 is continuous withthe semiconductor region 14. The semiconductor region 20 functions as achannel stop layer, and reduces a spread of a depletion layer betweenpixels. The semiconductor region 20 may be divided into a plurality ofregions when viewed in the direction orthogonal to the main surface 11b.

The semiconductor photodetector 1 includes a plurality of pad electrodes41, a plurality of UBMs (under-bump metals) 43, and a plurality of bumpelectrodes 45.

The respective pad electrodes 41 are disposed on the semiconductorregion 20. The respective pad electrodes 41 are disposed atpredetermined intervals when viewed in the direction orthogonal to themain surface 11 b. The pad electrode 41 is formed on the insulating film23. The pad electrode 41 is connected to the semiconductor region 20 viaa contact hole formed in the insulating film 23. The pad electrode 41 isin contact with the semiconductor region 20 and the insulating film 23.The pad electrode 41 is directly disposed on the semiconductor region20. The pad electrode 41 is in contact with the insulating film 25. Theinsulating film 25 covers peripheral edge of the pad electrode 41. Thepad electrode 41 is made of a conductive material. The pad electrode 41is made of aluminum, for example. In this case, the pad electrode 41 isformed with sputtering or vapor deposition.

The UBM 43 is disposed on the semiconductor region 20. The UBM 43 isformed on the semiconductor region 20 and the insulating film 25. TheUBM 43 is connected to the pad electrode 41 via a contact hole formed inthe insulating film 25. The UBM 43 is in contact with the pad electrode41. The UBM 43 is in contact with the insulating film 25. The UBM 43 ismade of a material having excellent electrical and physical connectionwith the bump electrode 45. For example, the UBM 43 is constituted by alaminated body constituted by a layer made of titanium and a layer madeof platinum. For example, the UBM 43 is formed with multilayer vapordeposition.

The bump electrode 45 is disposed on the semiconductor region 20. Thebump electrode 45 is formed on the UBM 43. The bump electrode 45 is incontact with the UBM 43. The UBM 43 is located between the pad electrode41 and the bump electrode 45. The bump electrode 45 is indirectlydisposed on the semiconductor region 20. The bump electrode 45 isindirectly disposed on the pad electrode 41. The bump electrode 45 iselectrically connected to the semiconductor region 20 via the UBM 43 andthe pad electrode 41. The bump electrode 45 is made of a soldermaterial. For example, the bump electrode 45 is made of indium. Forexample, the bump electrode 45 is formed with vapor deposition.

Next, a configuration of the electronic component device ED includingthe semiconductor photodetector 1 according to the first modificationwill be described with reference to FIG. 14. FIG. 14 is a viewillustrating a cross-sectional configuration of the electronic componentdevice that includes the back-illuminated semiconductor photodetectoraccording to the first modification.

The electronic component device ED includes the semiconductorphotodetector 1 according to the first modification, and the electroniccomponent EC. The electronic component EC includes a plurality of padelectrodes 71, a plurality of UBMs 73, and a plurality of bumpelectrodes 75. The plurality of pad electrodes 71, the plurality of UBMs73, and the plurality of bump electrodes 75 are disposed at positionscorresponding to the plurality of bump electrodes 35 and 45 included inthe semiconductor photodetector 1. The semiconductor photodetector 1 ismounted on the electronic component EC due to joining the bumpelectrodes 35 and 45 and the bump electrodes 75 associated with eachother.

Next, a configuration of the semiconductor photodetector 1 according toa second modification of the above embodiment will be described withreference to FIGS. 15 and 16. FIG. 15 is a view illustrating across-sectional configuration of a back-illuminated semiconductorphotodetector according to the second modification. FIG. 16 is a planview illustrating the configuration of the back-illuminatedsemiconductor photodetector according to the second modification. FIG.16 does not illustrate the insulating films 23 and 25. In FIG. 16, aregion corresponding to the textured surface TS is hatched to help easyunderstanding of a region constituted by the textured surface TS. Thesecond modification is substantially similar or identical to theembodiment described above. However, the second modification isdifferent from the above embodiment in the configuration of thesemiconductor substrate 11. Differences between the above embodiment andthe second modification will be hereinafter chiefly described.

A trench TR is formed in the semiconductor substrate 11 to separate therespective pixels from each other. The trench TR is opened in the mainsurface 11 b. The trench TR is formed to divide the semiconductor region20 when viewed in the direction orthogonal to the main surface 11 b. Thetrench TR has a grid shape in such a manner as to pass between thesemiconductor regions 15 adjacent to each other in the first direction,and between the semiconductor regions 15 adjacent to each other in thesecond direction when viewed in the direction orthogonal to the mainsurface 11 b. For example, the opening of trench TR has a width of 5 μm.The trench TR has a depth larger than the thickness TH2. For example,the trench TR has a depth of 50 μm. For example, the trench TR is formedwith reactive ion etching (RIE). The trench TR may be formeddiscontinuously when viewed in the direction orthogonal to main surface11 b. In this case, for example, a plurality of trenches extending inthe first direction when viewed in the direction orthogonal to the mainsurface 11 b, and a plurality of trenches extending in the seconddirection when viewed in the direction orthogonal to the main surface 11b are formed in the semiconductor substrate 11.

The insulating film 23 is formed on an inner surface (specifically, sidesurface and bottom surface) of the trench TR. The insulating film 23reaches the inside of the trench TR from the upper side of the mainsurface 11 b. The insulating film 25 is formed on the insulating film 23formed on the inner surface of the trench TR. The insulating film 25extends from the upper side of the insulating film 23 located on themain surface 11 b into the trench TR. A buried layer may be disposed inthe trench TR. The buried layer is made of metal, for example. In thiscase, the buried layer (metal layer) is formed with CVD or electrolyticplating, for example.

The trench TR prevents light reflected or diffused at the texturedsurface TS from traveling toward an adjacent pixel. Therefore, thesemiconductor photodetector 1 according to the second modificationfurther reduces generation of crosstalk. The trench TR also preventscarriers from moving between adjacent pixels.

The semiconductor photodetector 1 according to the second modificationmay be mounted on the electronic component EC as illustrated in FIG. 11.In this case, the electronic component device ED includes thesemiconductor photodetector 1 according to the second modification, andthe electronic component EC.

Next, a configuration of the semiconductor photodetector 1 according toa third modification of the above embodiment will be described withreference to FIGS. 17 and 18. FIG. 17 is a view illustrating across-sectional configuration of a back-illuminated semiconductorphotodetector according to the third modification. FIG. 18 is a planview illustrating a configuration of the back-illuminated semiconductorphotodetector according to the third modification. FIG. 18 does notillustrate the insulating films 23 and 25. In FIG. 18, a regioncorresponding to the textured surface TS is hatched to help easyunderstanding of a region constituted by the textured surface TS. Thethird modification is substantially similar or identical to theembodiment described above. However, the third modification is differentfrom the above embodiment in the configuration of the pad electrodes 31.Differences between the above embodiment and the third modification willbe hereinafter chiefly described.

The pad electrode 31 is disposed to cover the entire semiconductorregion 15 when viewed in the direction orthogonal to the semiconductorsubstrate 11. The electrode region 3 lb is indirectly disposed on anentire region included in the insulating film 23 and corresponding tothe region 17. The electrode region 3 lb overlaps with the entire edgeregion TSa that is continuous with the region 19 (regions 19 a, 19 b)when viewed in the direction orthogonal to the semiconductor substrate11. The pad electrode 31 overlaps with an entire boundary between theregion 17 and the region 19 when viewed in the direction orthogonal tothe semiconductor substrate 11. The pad electrode 31 is indirectlydisposed on the entire semiconductor region 15.

In a case where the pad electrodes 31 are made of Al, the pad electrodes31 may absorb light having reached the pad electrodes 31 (for example,near infrared light). Absorption of light by the pad electrodes 31deteriorates the spectral sensitivity characteristic in the longwavelength range.

In the semiconductor photodetector 1, the insulating films 23 and 25disposed on the textured surface TS reflect or diffuse the light havingreached the insulating films 23 and 25. Therefore, light transmittedthrough the insulating films 23 and 25 decreases. Consequently, thesemiconductor photodetector 1 reduces deterioration of the spectralsensitivity characteristics in the long wavelength range.

Next, a configuration of the semiconductor photodetector 1 according tofourth and fifth modifications of the above embodiment will be describedwith reference to FIGS. 19 and 20. FIG. 19 is a plan view illustratingthe configuration of a back-illuminated semiconductor photodetectoraccording to the fourth modification. FIG. 20 is a plan viewillustrating the configuration of a back-illuminated semiconductorphotodetector according to the fifth modification. FIGS. 19 and 20 donot illustrate the insulating films 23 and 25. In FIGS. 19 and 20, aregion corresponding to the textured surface TS is hatched to help easyunderstanding of a region constituted by the textured surface TS. Thefourth and fifth modifications are substantially similar or identical tothe embodiment described above. However, the fourth modification isdifferent from the above embodiment in the configuration of thesemiconductor regions 15, and the fifth modification is different fromthe above embodiment in the configuration of the semiconductor regions15 and the pad electrodes 31. Differences between the above embodimentand the fourth and fifth modifications will be hereinafter chieflydescribed.

As illustrated in FIG. 19, the regions 19 b is located at a center ofthe semiconductor region 15 when viewed in the direction orthogonal tothe semiconductor substrate 11. The region 19 b is separated from theregion 19 a. The region 17 (textured surface TS) is located between theregion 19 a and the region 19 b when viewed in the direction orthogonalto the semiconductor substrate 11. The electrode region 31 b overlapswith the entire edge region TSa that is continuous with the region 19 bwhen viewed in the direction orthogonal to the semiconductor substrate11. The pad electrode 31 overlaps with an entire boundary between theregion 17 and the region 19 b when viewed in the direction orthogonal tothe semiconductor substrate 11.

Similarly to the fourth modification, the region 19 b is located at thecenter of the semiconductor region 15 when viewed in the directionorthogonal to the semiconductor substrate 11 as illustrated in FIG. 20.Similarly to the third modification, the pad electrode 31 is disposed tocover the entire semiconductor region 15 when viewed in the directionorthogonal to the semiconductor substrate 11. The electrode region 31 boverlaps with the entire edge region TSa that is continuous with theregion 19 a, and the entire edge region TSa that is continuous with theregion 19 b when viewed in the direction orthogonal to the semiconductorsubstrate 11. The pad electrode 31 overlaps with an entire boundarybetween the regions 17 and 19 a, and an entire boundary between theregions 17 and 19 b when viewed in the direction orthogonal to thesemiconductor substrate 11.

In the configuration where the region 19 b is located at the center ofthe semiconductor region 15, a carrier moving distance is short, and atime from incidence of light to output of a signal is short as comparedwith in a configuration where the region 19 b is located at one cornerof the semiconductor region 15. Therefore, the semiconductorphotodetector 1 increases a response speed in each of the fourth andfifth modifications.

Next, a configuration of a semiconductor photodetector according to asixth modification of the present embodiment will be described withreference to FIG. 21. FIG. 21 is a plan view illustrating aconfiguration of a back-illuminated semiconductor photodetectoraccording to the sixth modification. FIG. 21 does not illustrate theinsulating films 23 and 25. In FIG. 21, a region corresponding to thetextured surface TS is hatched to help easy understanding of a regionconstituted by the textured surface TS. The sixth modification issubstantially similar or identical to the embodiment described above.However, the sixth modification is different from the above embodimentin the configuration of the semiconductor regions 15 and the padelectrodes 31. Differences between the above embodiment and the sixthmodification will be hereinafter chiefly described.

The region 17 and the region 19 b are adjacent to each other in thefirst direction when viewed in the direction orthogonal to thesemiconductor substrate 11. The region 17 and the regions 19 a and 19 bhave a rectangular shape when viewed in the direction orthogonal to thesemiconductor substrate 11. The region 19 b is located outside theregion 19 a. One side constituting an edge of the region 19 a is incontact with one side constituting an edge of the region 19 b. An areaof the region 19 b is smaller than an area of the region 19 a whenviewed in the direction orthogonal to the semiconductor substrate 11.The pad electrode 31 is not located on the region 17 (textured surfaceTS). That is, the pad electrode 31 does not include the electrode region31 b. The pad electrode 31 does not overlap with the textured surface TSwhen viewed in the direction orthogonal to the semiconductor substrate11. In the sixth modification, the semiconductor substrate 11 includesthe semiconductor region 20. However, the semiconductor substrate 11 isnot required to include the semiconductor region 20. The region 17 andthe region 19 b may be adjacent to each other in the second directionwhen viewed in the direction orthogonal to the semiconductor substrate11.

Next, a configuration of the semiconductor photodetector 1 according toa seventh modification of the above embodiment will be described withreference to FIGS. 22 and 23. FIG. 22 is a view illustrating across-sectional configuration of a back-illuminated semiconductorphotodetector according to the seventh modification. FIG. 23 is a viewillustrating a cross-sectional configuration of one pixel. In FIG. 23,hatching for indicating a cross section is omitted. The seventhmodification is substantially similar or identical to the embodimentdescribed above. However, the seventh modification is different from theabove embodiment in the configuration of the layer 37. Differencesbetween the above embodiment and the seventh modification will behereinafter chiefly described.

The semiconductor photodetector 1 includes a plurality of layers 37.Each of the layers 37 is disposed on the corresponding textured surfaceTS. Each of the layers 37 is in contact with the corresponding texturedsurface TS. The layer 37 is directly disposed on the textured surfaceTS. A surface of the layer 37 includes protrusions and recessescorresponding to the protrusions and recesses of the textured surfaceTS. For example, the surface of the layer 37 includes protrusions andrecesses approximately identical to the protrusions and recesses of thetextured surface TS. The layer 37 contains impurities of the secondconductivity type. In the seventh modification, the layer 37 containsp-type impurities. For example, the layer 37 contains boron. Forexample, the layer 37 is a metal layer containing boron. The layer 37may be constituted by only impurities of the second conductivity type.For example, the layer 37 has a thickness of 0.01 μm.

In the seventh modification, the insulating film 23 includes a region 23a and a region 23 b. The region 23 a is located on the textured surfaceTS. The region 23 a is disposed on the textured surface TS such that thelayer 37 is located between the textured surface TS and the region 23 a.The region 23 a is indirectly disposed on the textured surface TS. Theregion 23 b is located on the main surface 11 b. The region 23 b isdirectly disposed on the main surface 11 b. For example, the region 23 ais made of aluminum oxide. The region 23 b is made of silicon oxide. Forexample, the region 23 a has a thickness of 0.03 μm. For example, theregion 23 b has a thickness of 0.5 μm.

The region 17 of the semiconductor region 15 is formed along thetextured surface TS. A boundary interface between the region 17 and thesemiconductor region 13 includes protrusions and recesses correspondingto the protrusions and recesses of the textured surface TS. For example,the boundary interface between the region 17 and the semiconductorregion 13 includes protrusions and recesses approximately identical tothe protrusions and recesses of the textured surface TS. The region 17is formed due to diffusing the impurities contained in the layer 37 fromthe textured surface TS toward the semiconductor substrate 11. Theregion 19 of the semiconductor region 15 is formed along the mainsurface 11 b. The thickness TH3 of the region 17 in the thicknessdirection of the semiconductor substrate 11 is smaller than thethickness TH2 of the region 19 in the thickness direction of thesemiconductor substrate 11. For example, the thickness TH2 is 0.5 μm.For example, the thickness TH3 is 0.01 μm. The region 17 is formed alongthe textured surface TS as described above also in the seventhmodification. Therefore, the thickness TH3 tends not to change incorrespondence with the protrusions and recesses of the textured surfaceTS. In the seventh modification, the thickness TH3 is also approximatelyconstant, for example. The thickness TH1 of the region 17 at the deepestposition of the recesses of the textured surface TS is equal to thethickness TH3.

The semiconductor substrate 11 may include the semiconductor region 20similarly to the first modification. The trench TR may be formed in thesemiconductor substrate 11 similarly to the second modification. The padelectrodes 31 may be disposed to cover the entire semiconductor region15 similarly to the third modification. The region 19 b may be locatedat the center of the semiconductor region 15 when viewed in thedirection orthogonal to the semiconductor substrate 11, similarly to thefourth and fifth modifications. The region 17 and the region 19 b may beadjacent to each other in the first direction or the second directionwhen viewed in the direction orthogonal to the semiconductor substrate11, similarly to the sixth modification.

Next, an example of a manufacturing process of the semiconductorphotodetector 1 according to the seventh modification will be describedwith reference to FIGS. 24A to 25B. Each of FIGS. 24A to 25B is aschematic diagram illustrating an example of the manufacturing processof the back-illuminated semiconductor photodetector according to theseventh modification. In FIGS. 24A to 25B, hatching for indicating across section is omitted. Differences between the above embodiment andthe seventh modification in the manufacturing process will behereinafter chiefly described.

Processes performed until formation of the textured surface TS in thepresent embodiment are the same as the corresponding processes performedin the sixth modification. In FIGS. 24A to 25B, a cross-hatched regionis a region where the textured surface TS is formed. Also in FIGS. 24Ato 25B, only one planned region PR is illustrated.

As illustrated in FIG. 24A, the layer 37 is formed on the texturedsurface TS. For example, the layer 37 is formed with epitaxial growth.Thereafter, p-type impurities contained in the layer 37 diffuse into thesemiconductor substrate 11 due to a high temperature heat treatment.Consequently, the semiconductor region 15 ₂ is formed as illustrated inFIG. 24B. The semiconductor region 15 ₂ is constituted byhigh-concentration p-type impurities diffused from the layer 37. Sincethe p-type impurities diffuse from the textured surface TS, thesemiconductor region 15 ₂ is formed along the textured surface TS. Thep-type impurities also diffuse in the direction orthogonal to thethickness direction of the semiconductor substrate 11. Therefore, thep-type impurities existing in the semiconductor region 15 ₁ also diffusein the direction orthogonal to the thickness direction of thesemiconductor substrate 11. The semiconductor region 15 ₁ and thesemiconductor region 15 ₂ are continuously formed. The plurality ofsemiconductor regions 15 are formed in the semiconductor substrate 11with this process.

As illustrated in FIG. 24C, the pad electrode 31 is formed after thesilicon nitride film 57 is removed from the oxide film 51 and the oxidefilm 53. The semiconductor region 15 (semiconductor region 15 ₁) isexposed through the contact hole H1 due to removing the silicon nitridefilm 57. The pad electrode 31 is formed in such a manner as to contactthe region included in the semiconductor region 15 and exposed throughthe contact hole H1 with the same processes as the respectivecorresponding forming processes of the above embodiment. The oxide film51 constitutes the insulating film 21.

As illustrated in FIG. 25A, the aluminum oxide film 63 is formed on thelayer 37 due to patterning. The aluminum oxide film 63 corresponds tothe region 23 a of the insulating film 23. Thereafter, as illustrated inFIG. 25B, the insulating film 25, the UBM 33, and the bump electrode 35are formed by the same processes as the corresponding forming processesin the above embodiment. The semiconductor photodetector 1 according tothe seventh modification is obtained with these processes. The oxidefilm 53 and the aluminum oxide film 63 constitute the insulating film23.

Also in the manufacturing process of the seventh modification, theplurality of semiconductor regions 15 (the plurality of semiconductorregions 15 ₂) are formed in the plurality of planned regions PR afterthe textured regions are formed in the main surface 11 b, similarly tothe manufacturing process of the present embodiment. The manufacturingprocess of the seventh modification is different from the manufacturingprocess of the present embodiment in the process of forming thesemiconductor regions 15 ₂. In the manufacturing process of the presentembodiment, the semiconductor regions 15 ₂ are formed in thesemiconductor substrate 11 due to diffusing the impurities (p-typeimpurities) existing inside the semiconductor substrate 11. In contrast,in the manufacturing process of the seventh modification, thesemiconductor regions 15 ₂ are formed in the semiconductor substrate 11due to diffusing the impurities (p-type impurities) existing on thesurface of the semiconductor substrate 11 into the semiconductorsubstrate 11. In this case, a diffusion distance of impurities is short.Therefore, the thickness of the semiconductor region 15 ₂ obtained inthe manufacturing process of the seventh modification can be madesmaller than the thickness of the semiconductor region 15 ₂ obtained inthe manufacturing process of the present embodiment. Consequently, thesemiconductor photodetector 1 according to the seventh modification canfurther improve the spectral sensitivity characteristics in the longwavelength range. Actually, the thickness of each of the semiconductorregions 15 ₂ of the seventh modification is smaller than the thicknessof each of the semiconductor regions 15 ₁ and 15 ₂ of the presentembodiment.

Also in the manufacturing process of the seventh modification, thesemiconductor region 15 ₂ (regions 17) is formed along the surface shapeof the textured region similarly to the present embodiment. In thiscase, the thickness of the semiconductor region 15 ₂ (region 17) can befurther reduced. Therefore, the semiconductor photodetector 1 canfurther improve the spectral sensitivity characteristics in the longwavelength range with reliability.

In the manufacturing process of the seventh modification, thesemiconductor regions 15 ₂ (region 17) are formed due to forming thelayers 37. In this case, the semiconductor region 15 ₂ having a smallthickness is formed reliably and easily.

In the seventh modification, the region (region 23 a) included in theinsulating film 23 and located on the textured surface TS is constitutednot by a silicon thermal oxide film, but by the aluminum oxide film 63.

In a case where the region (region 23 a) located on the textured surfaceTS is constituted by a silicon thermal oxide film, the textured surfaceTS is oxidized. Oxidation of the textured surface TS tends to reduce aneffect of improving the spectral sensitivity characteristic in the longwavelength range. In the seventh modification, the region 23 a isconstituted not by a silicon thermal oxide film, but by the aluminumoxide film 63. Therefore, the seventh modification tends not to reducethe effect of improving the spectral sensitivity characteristic in thelong wavelength range. For example, the region 23 a may be constitutedby a silicon nitride film. For example, the silicon nitride film isformed with low pressure CVD.

Although the embodiment and the modifications of the present inventionhave been described, the present invention is not necessarily limited tothe embodiment and the modifications described above, but may bemodified in various ways without departing from the spirit of thepresent invention.

The textured surface TS may be provided in a region of the main surface11 b other than the semiconductor region 15. In a case where thetextured surface TS is provided for each of the semiconductor regions15, the semiconductor photodetector 1 reduces generation of thecrosstalk as described above.

The textured surface TS is not required to be located toward the mainsurface 11 a in comparison to the surface of the region 19 in thethickness direction of the semiconductor substrate 11. That is, thetextured surface TS is not required to be located toward the mainsurface 11 a in comparison to the virtual plane VP. For example, the topof the textured surface TS may be located at the same position as thevirtual plane VP. In a case where the textured surface TS is locatedtoward the main surface 11 a in comparison to the virtual plane VP, thesemiconductor photodetector 1 reduces generation of the dark currents asdescribed above.

The edge region TSa is not required to be continuous with the surface ofthe region 19. For example, the edge region TSa may be separated fromthe step formed by the regions 17 and 19. For example, a region notincluding the textured surface TS may be located between the edge regionTSa and the step formed by the regions 17 and 19. In this case, forexample, the entire edge region TSa may be surrounded by the region notincluding the textured surface TS when viewed in the directionorthogonal to the semiconductor substrate 11. For example, the region 17may include a region not including the textured surface TS.

The edge region TSa may be approximately parallel to the thicknessdirection of the semiconductor substrate. In a case where the edgeregion TSa is inclined to the thickness direction of the semiconductorsubstrate 11, the semiconductor photodetector 1 further decreasesgeneration of the dark currents as described above.

The bump electrode 35 may be directly disposed on the pad electrode 31.In this case, the semiconductor photodetector 1 does not include theUBMs 33.

INDUSTRIAL AVAILABILITY

The present invention is applicable to a method for manufacturing aback-illuminated semiconductor photodetector.

REFERENCE SIGNS LIST

-   1 Back-illuminated semiconductor photodetector-   11 Semiconductor substrate-   11 a, 11 b Main surface-   13, 15, 15 ₁, 15 ₂ Semiconductor region-   TS Textured surface-   PR Planned region

1. A back-illuminated semiconductor photodetector comprising asemiconductor substrate including a first main surface and a second mainsurface opposing each other, wherein the semiconductor substrateincludes a first semiconductor region of a first conductivity type, anda plurality of second semiconductor regions of a second conductivitytype, the second semiconductor regions provided in a side of the secondmain surface and forming pn junctions with the first semiconductorregion, the plurality of second semiconductor regions include a regionincluding a textured surface, the second semiconductor region isprovided along the textured surface, in the region including thetextured surface, the first main surface is a light incident surface ofthe semiconductor substrate.
 2. The back-illuminated semiconductorphotodetector according to claim 1, wherein each of the plurality ofsecond semiconductor regions includes added impurities of the secondconductivity type.
 3. The back-illuminated semiconductor photodetectoraccording to claim 2, wherein the impurities of the second conductivitytype include boron.
 4. The back-illuminated semiconductor photodetectoraccording to claim 1, wherein each of the plurality of secondsemiconductor regions is constituted a layer containing impurities ofthe second conductivity type.
 5. The back-illuminated semiconductorphotodetector according to claim 4, wherein the impurities of the secondconductivity type include boron.
 6. The back-illuminated semiconductorphotodetector according to claim 1, wherein a boundary interface betweenthe first semiconductor region and each of the plurality of secondsemiconductor regions includes protrusions and recesses corresponding toprotrusions and recesses included in a surface of the texture region, inthe region including the textured surface.
 7. The back-illuminatedsemiconductor photodetector according to claim 1, wherein a boundaryinterface between the first semiconductor region and each of theplurality of second semiconductor regions includes protrusions andrecesses that are more gradual than protrusions and recesses included ina surface of the texture region, in the region including the texturedsurface.